Add to rc.local
su - username -c 'byobu -d -m -S glances glances'
- -d
 - for detaching
 - -m
 - for a new session
 - -S glances
 - for changing the name of the tab
 
And for adding a new tab to an already running instance, add to rc.local:
su - username -c 'byobu -X screen -S htop htop'